Journal of the American Chemical Society p. 6363 - 6367 (1985)
Update date:2022-08-25
Topics:
Chiang, Y.
Kresge, A. J.
Rates of hydration of cis- and trans-cyclooctene and 2,3-dimethyl-2-butene to the corresponding alcohols have been measured in concentrated and dilute aqueous perchloric acid, and those of the latter two olefins in bisulfate ion and phosphoric acid buffer solutions as well.The systems examined in buffers show general-acid catalysis.The reaction of trans-cyclooctene is not reversible, but those of cis-cyclooctene and 2,3-dimethyl-2-butene are; for cis-cycloctene, K=
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