Chemistry Letters p. 701 - 702 (1996)
Update date:2022-08-17
Topics:
Nakano, Hideyuki
Akamatsu, Keiichi
Moriwaki, Kazuyuki
Shirota, Yasuhiko
For the purpose of gaining information on the microstructure of molecular glasses, photochromic behavior of 4-dimethyl-aminoazobenzene (DAAB) in the molecular glass of 4,4′,4″-tris(3-methylphenylphenylamino)triphenylamine (m-MTDATA) was studied in comparison with that in a polystyrene matrix and in a benzene solution. The results strongly suggest that the local free volume in the molecular glass of m-MTDATA is smaller than that in the polystyrene glass.
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