α-Aryl O-vinyl carbamates. Tandem carbolithiation - α-alkylation and -[1,2]-Wittig rearrangement reactions

DOI: 10.1016/0040-4039(96)01315-9

Source and publish data:

Tetrahedron Letters p. 6061 - 6064 (1996)

Update date:2022-08-10

Topics:

Authors:

Superchi, Stefano

Sotomayor, Nuria

Miao, Guobin

Joseph, Babu

Campbell, Michael G.

Snieckus, Victor

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Article abstract of DOI:10.1016/0040-4039(96)01315-9

Efficient, one-pot carbolithiation - α-alkylation and -[1,2]-Wittig rearrangement processes of α-aryl O-vinyl carbamates 1 to branched benzyl O-carbamates 3 and 2-aryl-2-hydroxypropionamides 4, including Naproxen analogues, is described.

Full text of DOI:10.1016/0040-4039(96)01315-9

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