Tetrahedron Letters p. 2421 - 2424 (1988)
Update date:2022-08-11
Topics:
Hagen, Timothy J.
Cook, James M.
The six step synthesis of the cytotoxic antileukemic alkaloid 1-methoxy canthine-6-one 2 is described.The pivotal steps are represented by the oxidation (DDQ) of 9 to afford the 3-acylindole 14 and the conversion of 11 into the 4-methoxy-1-alkyl β-carboline 15.
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