Journal of the American Chemical Society
Article
Pd(OAc)2-catalyzed trifluoromethylation, see (b) Wang, X.; Truesdale,
L.; Yu, J.-Q. J. Am. Chem. Soc. 2010, 132, 3648−3649.
Notes
The authors declare no competing financial interest.
(9) Trifluoromethyl Pd(IV) complexes supported by bipyridyl
ligands have been reported: (a) Ball, N. D.; Kampf, J. W.; Sanford,
M. S. J. Am. Chem. Soc. 2010, 132, 2878−2879. (b) Ball, N. D.; Gary, J.
B.; Ye, Y.; Sanford, M. S. J. Am. Chem. Soc. 2011, 133, 7577−7584.
(c) Maleckis, A.; Sanford, M. S. Organometallics 2011, 30, 6617−6627.
(d) Racowski, J. M.; Ball, N. D.; Sanford, M. S. J. Am. Chem. Soc. 2011,
133, 18022−18025.
ACKNOWLEDGMENTS
■
We thank D. Ford (Harvard) for helpful discussions, A. Togni
and E. Maennel (ETH Zurich) for helpful discussions and
providing unpublished data concerning the X-ray crystal
structure of compound 7, S.-L. Zheng and T. M. Powers
(Harvard) for X-ray crystallographic analysis, the Australian
National Computational Infrastructure and the University of
Tasmania for computing resources, the AFOSR (FA9550-10-1-
0170), the NSF (CHE-0952753 and CHE-1111563), and the
Australian Research Council for financial support.
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experiments, saturation was not observed.
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