Synthesis of Hydroxy Ketones by Chemoselective Alkylation of Keto Aldehydes with Dialkylzincs Catalyzed by Amino Alcohol, Diamine, or Dilithium Salt of Piperazine

DOI: 10.1246/bcsj.62.2124

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2124 - 2125 (1989)

Update date:2022-08-10

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Authors:

Soai, Kenso

Watanabe, Masami

Koyano, Masashi

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Article abstract of DOI:10.1246/bcsj.62.2124

Hydroxy ketones were obtained in high yields by the chemoselective alkylation of formyl group of keto aldehydes with dialkylzincs in the presence of such catalysts as 2-dimethylaminoethanol, N,N,N',N'-tetramethylethylenediamine, ordilithium salt of pipera

Full text of DOI:10.1246/bcsj.62.2124

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