Corrigendum to: Aryl(triethyl)silanes for Biaryl and Teraryl Synthesis by Copper(II)-Catalyzed Cross-Coupling Reaction (Angew. Chem. Int. Ed., (2016), 55, (15787–15791), (10.1002/anie.201608667))

Article abstract of DOI:10.1002/anie.201705119

In this Communication, Table 3, entry 11, the correct product from the reaction of 2-(triethylsilyl)indole (6 b) with p-iodoanisole (4 a) was not 2-(p-methoxyphenyl)indole (7 ba) but N-(p-methoxyphenyl)indole [Eq. 1]. (Figure presented.) C2 arylation was achieved using substituted 2-(triethylsilyl)indoles. From the reaction of N-methyl-2-(triethylsilyl)indole with 4 a under standard conditions (reaction time was 22 h), N-methyl-2-(p-methoxyphenyl)indole was isolated in 52% yield after column chromatography [Eq. 2]. (Figure presented.) A corrected Supporting Information is provided along with this Corrigendum.

Full text of DOI:10.1002/anie.201705119

Angewandte
Contents
Chemie
.
Angewandte
Corrigendum
In this Communication, Table 3, entry 11, the correct product from the reaction of
-(triethylsilyl)indole (6b) with p-iodoanisole (4a) was not 2-(p-methoxyphenyl)indole
7ba) but N-(p-methoxyphenyl)indole [Eq. (1)].
Aryl(triethyl)silanes for Biaryl and Teraryl
Synthesis by Copper(II)-Catalyzed Cross-
Coupling Reaction
2
(
T. Komiyama, Y. Minami,*
T. Hiyama*
15787–15791
Angew. Chem. Int. Ed. 2016, 55
DOI: 10.1002/anie.201608667
C2 arylation was achieved using substituted 2-(triethylsilyl)indoles. From the reaction of
N-methyl-2-(triethylsilyl)indole with 4a under standard conditions (reaction time was
2
2 h), N-methyl-2-(p-methoxyphenyl)indole was isolated in 52% yield after column
chromatography [Eq. (2)].
A corrected Supporting Information is provided along with this Corrigendum.
Angew. Chem. Int. Ed. 2017, 56, 8021 – 8035
ꢀ 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
www.angewandte.org
8035