Journal of the Chemical Society. Chemical communications p. 260 - 261 (1988)
Update date:2022-08-17
Topics:
Amir-Ebrahimi, Valia
Rooney, John J.
Isomerization of protoadamantane to adamantane and of bicyclo<2.2.2>octane to bicyclo<3.2.1>octane occurs on reduced molybdenum powder or on reduced molybdena/alumina catalysts in excess of hydrogen at >/= 275 deg C; an olefin metathesis-type mechanism is precluded by the structures of these caged compounds, so simple bond shift in alkyl radicals on transition metal surfaces seems to be generally valid reaction pathway in heterogenous conversions of paraffins.
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