Organic Mass Spectrometry p. 486 - 492 (1987)
Update date:2022-08-11
Topics:
Svendsen, John S.
Whist, Jon E.
Sydnes, Leiv K.
The fragmentation pathways for the dimethyl ester trimethylsilyl enol ether derivatives of some 3-oxodicarboxylic acids have been found by using B/E and B2/E linked scans, collisional activated decomposition and isotope substitution techniques.The trimethylsilyloxy group strongly directs the decomposition processes, and induces a fragmentation pattern that intimately reflects the structure of the compounds.
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