Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 2121 - 2128 (1982)
Update date:2022-08-24
Topics:
Anpo, Masakazu
Tanahashi, Ichiro
Kubokawa, Yutaka
Ultraviolet irradiation of MoO3 supported on porous Vycor glass (PVG) in the presence of C3H4 has been found to induce the formation of approximately equimolar amounts of C2H4 and 2-C4H8 as well as a small amount of CH3CHO, suggesting that the metathesis reaction of C3H4 occurs.The dependence of the yields upon the excitation wavelenght is in good agreement with the excitation band of the phosphorescence of MoO3/PVG, wich arises from the charge-transfer transition
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Doi:10.1021/ja01684a006
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