Raman spectroscopic study of allyl methyl ether (3-methoxy-1-propene), CH2=CHCH2OCH3, and some isotopically labelled analogues

Article abstract of DOI:10.1016/0022-2860(95)08852-M

Fourier-transform Raman spectra of allyl methyl ether, CH2=CHCH2OCH3, three deuterated derivatives and one 13C derivative have been obtained.Comparison of the spectra of the deuterated and protiated compounds in conjunction with polarization data has enabled full vibrational assignments to be made for the carbon-hydrogen modes and the 13C data have identified some skeletal modes of the CO and CC bonds.As a result of the data obtained from the deuterated compounds in particular, some initial suggestions have been revised for tentative literature assignments of molecules of biological interest.In other cases, confirmation of existing assignments have been made.