Sulfoniosilylation of α,β-Unsaturated Carbonyl Compounds. Facile Nucleophilic Substitution of 3-Trialkylsilyloxyalk-2-enylenesufonium Salts

DOI: 10.1039/c39930001188

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1188 - 1189 (1993)

Update date:2022-08-10

Topics:

Authors:

Kim, Sunggak

Park, Joo Hyeon

Kim, Yong Gil

Lee, Joo Moon

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39930001188

Sulfoniosilylation of α,β-enones and α,β-enals with trialkylsilyl triflate and dimethyl sulfide at -78 deg C affords 3-trialkylsilyloxyalk-2-enylenesulfonium salts, which undergo facile nucleophilic substitution with various nucleophiles.

Full text of DOI:10.1039/c39930001188

View Online / Journal Homepage / Table of Contents for this issue

View Online

Products guided by the article

Product name:Silane, (1-cyclohexen-1-yloxy)(1,1-dimethylethyl)dimethyl-

Cas No:62791-22-4

R&D Labs maybe for 62791-22-4

Shanghai AoBo Bio-Pharmaceutical Technology Co., Ltd.

Contact:+86-21-51320130-801, 816

Address:Room 601, No. 1011, Halei Road, Zhangjiang High-Tech Park, Pudong, Shanghai
Chemsigma International Co.,Ltd.

website:http://www.chemsigma.com

Contact:86-025-58748998

Address:Rm.705, 15th Building,Rd.Xinke II
Xi'an Galaxy Chemicals CO., Ltd

Contact:86-29-89380370

Address:No.8, Gaoxin three road, Xi'an city.
Shanghai Profirst Co., Ltd.

Contact:+86-21-38122007

Address:2, Lane 1123, Kangqiao Road, Pudong New Area, Shanghai
HAINAN JINYING IMPORT AND EXPORT CO. LTD

Contact:+86-898-32875423

Address:A SECTION 19TH FL, TIMES SQUARE, NO.2 GUO MAO AVENUE HAIKOU, HAINAN, P. R. OF CHINA

Relevant to this article

A molecular mechanism for the chemoselective hydrogenation of substituted nitroaromatics with nanoparticles of gold on TiO₂ catalysts: A cooperative effect between gold and the support

Doi:10.1021/ja076721g
(2007)
Noncovalent Interactions Drive the Efficiency of Molybdenum Imido Alkylidene Catalysts for Olefin Metathesis

Doi:10.1021/jacs.9b04367
(2019)
Doi:10.1039/JR9650005045
()
Synthesis of Enantiomerically Pure (S)-(+)-3-Hydroxytetrahydrofuran and Its R Enantiomer from Malic or Tartaric Acid

Doi:10.1021/jo00164a027
(1983)
Reductive acylamination of pyridine N-oxide with aminopyridines and their N-p-tolylsulfonyl derivatives

Doi:10.1007/s11178-005-0134-x
(2005)
Topochemical polymerization of dumbbell-shaped diacetylene monomers: Relationship between chemical structure, molecular packing structure, and gelation property

Doi:10.1039/c7sm01166k
(2017)

Article Doi