Sulfoniosilylation of α,β-Unsaturated Carbonyl Compounds. Facile Nucleophilic Substitution of 3-Trialkylsilyloxyalk-2-enylenesufonium Salts

DOI: 10.1039/c39930001188

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1188 - 1189 (1993)

Update date:2022-08-10

Topics:

Authors:

Kim, Sunggak

Park, Joo Hyeon

Kim, Yong Gil

Lee, Joo Moon

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39930001188

Sulfoniosilylation of α,β-enones and α,β-enals with trialkylsilyl triflate and dimethyl sulfide at -78 deg C affords 3-trialkylsilyloxyalk-2-enylenesulfonium salts, which undergo facile nucleophilic substitution with various nucleophiles.

Full text of DOI:10.1039/c39930001188

View Online / Journal Homepage / Table of Contents for this issue

View Online

Products guided by the article

Product name:Silane, (1-cyclohexen-1-yloxy)(1,1-dimethylethyl)dimethyl-

Cas No:62791-22-4

R&D Labs maybe for 62791-22-4

ShiJiaZhuang Dowell Chemical Co.,Ltd.

website:http://www.dowechem.com

Contact:+86-13463963265

Address:Xiyangling village, high tech Zone, Shijiazhuang，Hebei, China
Shanghai Forever Biotech Co., Ltd.

Contact:+86-21-69734790

Address:Room 5017/5019、5022、5024 of Technology Innovation Centre, No.1155, Gongyuan East Rd, QingPu District, Shanghai China.
TIANJIN DONGRUXIANG MINERALS MARKETING CO.,LTD(expird)

Contact:22-58516360

Address:tianjin
Xian Lyphar Biotech Co., Ltd.

Contact:0086-29-89196322

Address:North of the Fifth Keji Road, Hi-Tech Industrial Zone, Xi'an City, Shaanxi Province, China
SuZhou Bichal Biological Technology CO.,LTD

Contact:+86-512-68051130

Address:NO.32 huoju road HI-TECH Industrial development zone SuZhou China

Relevant to this article

A molecular mechanism for the chemoselective hydrogenation of substituted nitroaromatics with nanoparticles of gold on TiO₂ catalysts: A cooperative effect between gold and the support

Doi:10.1021/ja076721g
(2007)
Noncovalent Interactions Drive the Efficiency of Molybdenum Imido Alkylidene Catalysts for Olefin Metathesis

Doi:10.1021/jacs.9b04367
(2019)
Doi:10.1039/JR9650005045
()
Synthesis of Enantiomerically Pure (S)-(+)-3-Hydroxytetrahydrofuran and Its R Enantiomer from Malic or Tartaric Acid

Doi:10.1021/jo00164a027
(1983)
Reductive acylamination of pyridine N-oxide with aminopyridines and their N-p-tolylsulfonyl derivatives

Doi:10.1007/s11178-005-0134-x
(2005)
Topochemical polymerization of dumbbell-shaped diacetylene monomers: Relationship between chemical structure, molecular packing structure, and gelation property

Doi:10.1039/c7sm01166k
(2017)

Article Doi