Sulfoniosilylation of α,β-Unsaturated Carbonyl Compounds. Facile Nucleophilic Substitution of 3-Trialkylsilyloxyalk-2-enylenesufonium Salts

DOI: 10.1039/c39930001188

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1188 - 1189 (1993)

Update date:2022-08-10

Topics:

Authors:

Kim, Sunggak

Park, Joo Hyeon

Kim, Yong Gil

Lee, Joo Moon

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39930001188

Sulfoniosilylation of α,β-enones and α,β-enals with trialkylsilyl triflate and dimethyl sulfide at -78 deg C affords 3-trialkylsilyloxyalk-2-enylenesulfonium salts, which undergo facile nucleophilic substitution with various nucleophiles.

Full text of DOI:10.1039/c39930001188

View Online / Journal Homepage / Table of Contents for this issue

View Online

Products guided by the article

Product name:Silane, (1-cyclohexen-1-yloxy)(1,1-dimethylethyl)dimethyl-

Cas No:62791-22-4

R&D Labs maybe for 62791-22-4

Lonzeal Pharmaceuticals Co., Ltd.

website:http://www.lonzeal.com

Contact:+86-13381011962

Address:RM 801, Yue MOMA, No. 26 Anningzhuang Rd. Haidian District, Beijing, China
Jiangsu Haian Petro chemical Plant

Contact:+86-513-88902723

Address:99, Changjiang West Road, Haian County, Jiangsu
Rely Chemicals Ltd.

Contact:+86-518-81061113

Address:No. 8 Lingzhou Road, Lianyungang, Jiangsu, China
ChengduChroma-BiotechCo.,Ltd.

Contact:86-28-61993785

Address:No.70-13-21, North Section, Erhuan
Shanghai shibo Chemical Co., Ltd

Contact:+86-021-60753516

Address:688 Qiushi Road, Jinshan High-tech Park, Shanghai, China,201512

Relevant to this article

A molecular mechanism for the chemoselective hydrogenation of substituted nitroaromatics with nanoparticles of gold on TiO₂ catalysts: A cooperative effect between gold and the support

Doi:10.1021/ja076721g
(2007)
Noncovalent Interactions Drive the Efficiency of Molybdenum Imido Alkylidene Catalysts for Olefin Metathesis

Doi:10.1021/jacs.9b04367
(2019)
Doi:10.1039/JR9650005045
()
Synthesis of Enantiomerically Pure (S)-(+)-3-Hydroxytetrahydrofuran and Its R Enantiomer from Malic or Tartaric Acid

Doi:10.1021/jo00164a027
(1983)
Reductive acylamination of pyridine N-oxide with aminopyridines and their N-p-tolylsulfonyl derivatives

Doi:10.1007/s11178-005-0134-x
(2005)
Topochemical polymerization of dumbbell-shaped diacetylene monomers: Relationship between chemical structure, molecular packing structure, and gelation property

Doi:10.1039/c7sm01166k
(2017)

Article Doi