Journal of Organic Chemistry p. 3910 - 3911 (1986)
Update date:2022-08-31
Topics:
Squillacote, Michael E.
Bergman, Adelle
High-temperature equilibrium constants of trapped mixtures of 1,3,5,7-cyclooctatetraene and its valence tautomer bicyclo<4.2.0>octa-2,4,7-triene were obtained by using a high-temperature thermal trapping technique and gave values for the thermodynamic parameters ΔS0 and ΔH0 of -4.3 +/- 0.7 eu and 5.5 +/- 0.6 kcal/mol, respectively.
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