Preparation and Interconversion of Dithiatriazine Derivatives: Crystal, Molecular, and Electronic Structure of Bis(5-phenyl-1,3,2,4,6-dithiatriazine) (PhCN3S2)2

Article abstract of DOI:10.1021/ja00311a081

The reaction of N,N,N'-tris(trimethylsilyl)benzamide with S3N3Cl3 yields PhCN5S3, a bicyclic 5-phenyl1,3,2,4,6-dithiatriazine derivative with an -NSN- unit bridging the 1,3-sulfur atoms.Oxidation of this compound with chlorine produces 5-phenyl-1,3-dichlo