Chemistry of Heterocyclic Compounds p. 296 - 302 (1995)
Update date:2022-08-30
Topics:
Borovkov, V. V.
Evstigneeva, R. P.
Gribkov, A. A.
We describe methods for synthesis of a triad molecular system based on mesoporphyrin II with electron-donor and electron-acceptor moieties for modeling the primary stage of charge separation in photosynthesis, differing in the order of addition of the donor and the acceptor.Using fluorescent spectroscopy, we have demonstrated quenching-containing coppounds.Investigation of the triad and its zinc complex by kinetic fluorescent spectroscopy allowed us to determine the electron transfer rate constants for the triad and for its zinc complex.
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