Journal of the Chemical Society, Dalton Transactions p. 2102 - 2107 (1980)
Update date:2022-08-16
Topics:
Gillard, R. D.
Houghton, Roy P.
Tucker, John N.
In water and in dimethyl sulphoxide, hydroxide anion adds reversibly to position 6 of 5-nitro-1,10-phenanthroline to give an anion whose equilibrium constant of formation (in water) at 20 deg C is 1.2 +/- 0.1 dm3 mol -1.When heated in aqueous media, this anion rearranges to the anion of the mono-oxime of 1,10-phenanthroline-5,6-quinone.A further reaction then affords ammonia in high yield and whose nitrogen atom is derived entirely from the nitro-group of the nitrophenanthroline, and 4,5-diazafluoren-9-one as the major organic product.
View MoreBeijing Green Guardee Technology CO,.LTD
Contact:+86-10-69706062
Address:F2 BLdj,5 No.37 Chaoqian Road
SHOUGUANG BOYU CHEMICAL CO.,LTD
Contact:+86-536-8256719
Address:ROOM 1101&1103,BUILDING D,ZHONGTU MANSION,NO.6565 EAST FUSHOU STREET,WEIFANG CITY,SHANDONG,CHINA.
Shandong Ailitong New Material Co.,Ltd
Contact:+86-536-3226266
Address:zhongjia village, putong town , qingzhou city,Shandong Province,China
Contact:+86-533-3112891
Address:zibo
Contact:21-7631221 15884421033
Address:326 Science and technology,Shanghai,China
Doi:10.1002/pola.26339
(2013)Doi:10.1016/j.tetlet.2008.10.048
(2008)Doi:10.1021/ja00365a039
(1982)Doi:10.1134/S107042800901014X
(2009)Doi:10.1007/s00044-020-02617-1
(2020)Doi:10.1021/jo01285a027
(1967)
