Homogeneously Catalysed Disproportionation of Acetaldehyde into Ethanol and Acetic Acid

DOI: 10.1039/c39800000144

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 144 - 145 (1980)

Update date:2022-08-15

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Authors:

Cook, John

Hamlin, John E.

Nutton, Andrew

Maitlis, Peter M.

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Article abstract of DOI:10.1039/c39800000144

The complexes ⁺ (1), , M = Rh or Ir, , and ⁺ all catalyse the disproportionation of acetaldehyde to acetic acid and ethanol in water in the absence of base, and other aldehydes react similarly; rhodium hydride complexes can be isolated from the reactions involving (1).

Full text of DOI:10.1039/c39800000144

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