Activation of Molecular Oxygen Using Durable Cobalt Encapsulated with Nitrogen-Doped Graphitic Carbon Shells for Aerobic Oxidation of Lignin-Derived Alcohols

Article abstract of DOI:10.1002/chem.201705824

It has long been a challenge for activating O₂ by transition-metal nanocatalysts, which might lose activity due to strong tendency for oxidation. Herein, O₂ could be activated by durable encapsulated cobalt nanoparticles (NPs) with N-doped graphitic carbon shells (Co@N-C), but not by encapsulated cobalt NPs with graphitic carbon, exposed cobalt NPs supported on activated carbon, or N-doped carbon. Electron paramagnetic resonance, real-time in situ FTIR spectroscopy, and mass spectrometry measurements demonstrated the generation of the highly active superoxide radical, O₂^.?. This unique ability enables Co@N-C to afford an excellent catalytic performance in model aerobic oxidation of monomeric lignin-derived alcohols. Further analysis elucidated that encapsulated cobalt and nitrogen-doped graphitic carbon might contribute to the capacity through influencing the electronic properties of outer layers. Moreover, through isolation by N-doped graphitic carbon shells, the inner metallic cobalt NPs are inaccessible in term of either alcohols or oxygenated products, and a distinctive resistance to leaching and agglomeration has been achieved.