
Tetrahedron Letters p. 327 - 330 (1996)
Update date:2022-08-11
Topics:
Engler, Thomas A.
Agrios, Konstantinos
Reddy, Jayachandra P.
Iyengar, Rajesh
In Ti(IV)-promoted reactions with 2-methoxy-1,4-benzoquinones 3, thioallenes 1 give 2 + 2 and/or 3 + 2 products via attack on a C = C moiety of the quinone, whereas silylallene 2 gives products derived from attack on a carbonyl group of the quinone.
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