Journal of molecular catalysis p. 276 - 283 (1989)
Update date:2022-08-16
Topics:
Ogura
Migita
Nagaoka
Carbon dioxide has been reduced catalytically to methanol with an electrode mediator and homogeneous catalysts, using a hydrogen fuel cell as an energy source to regenerate the active mediator. Thermodynamic assessment predicts that the reversible potential for the reaction H+ + e- = 1/2 H2 should be more negative than that for the reaction CO2 + 6H+ + 6e- = CH3OH + H2O whenever a fuel cell with hydrogen as the fuel and CO2 as the oxidant is feasible. As reaction proceeded, the pH of the catholyte rose but that of the anolyte dropped, until finally reduction of CO2 ceased. Hence, adjustment of the pH values in both temperatures was necessary to maintain CO2 reduction over long time periods.
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