COMPARATIVE HAMETT STUDIES OF IMIDOYL, BENZYLIC, ALDEHYDIC HYDROGENS TRANSFER AND RELATED REACTION BY t-BUTOXYL RADICAL.

Article abstract of DOI:10.1016/S0040-4039(00)61957-3

The polar transition states involved in the hydrogen transfer reactions of N-benzylideneanilines, toluenes, benzaldehydes, and anisoles by t-butoxyl radical in benzene at 130 deg C have been comparatively discussed in terms of the values of the ? and the k^o_a/k_d.