ELIMINATION OF HYDROGEN FLUORIDE FROM FLUOROSUCCINIC ACIDS. KINETICS OF DEHYDROGLUORINATION OF 2,2-DIFLUOROSUCCINIC ACID

DOI: 10.1016/S0022-1139(00)81491-8

Source and publish data:

Journal of Fluorine Chemistry p. 73 - 80 (1983)

Update date:2022-08-11

Topics:

Authors:

Hudlicky, M.

Hall, J. A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0022-1139(00)81491-8

Elimination of hydrogen fluoride from 2,2difluorosuccinic acid was found to follow second order kinetics with the activation energy of 16.9 kcal/mol.The probable mechanism is bimolecular trans-elimination giving fluorofumaric acid.No hydrogen-deuterium exchange was observed.

Full text of DOI:10.1016/S0022-1139(00)81491-8

Products guided by the article

Product name:2-fluorofumarate

Cas No:672-18-4

R&D Labs maybe for 672-18-4

Changzhou Screw International Trading Co., Ltd.

Contact:13906149256,18001495888

Address:Jiangsu，Jintanqu
Suns Chemical Sdn Bhd

Contact:0086 371 65711996

Address:Jalan 4/3, Kawasan Perindustrian Serendah, 48000 Rawang,
Changzhou Anyi Biochem Co., Ltd.(expird)

Contact:+86-519-88836158

Address:no,51 caoda
C-LAB Chemievermittlung GmbH

Contact:+49-9398-993127

Address:Untertorstr. 27
Xinchang Yueding Chemical Co., Ltd.

Contact:86-571-56926323

Address:NO.90 BEIMENCHENGWAI CHENGGUAN TOWN XINCHANG

Relevant to this article

Doi:10.1021/jo01165a009
(1947)
Doi:10.1039/j29660000709
(1966)
Inhibition of cathepsin D by tripeptides containing statine analogs

Doi:10.1016/S0006-2952(99)00103-3
(1999)
Multifunctional catalyst based on sandwich-type polyoxotungstate and MIL-101 for liquid phase oxidations

Doi:10.1016/j.cattod.2012.12.003
(2013)
Palladium-catalyzed synthesis of tryptamines and tryptamine homologues: synthesis of psilocin

Doi:10.1016/j.tet.2009.09.050
(2009)
Intramolecular cycloaddition of geminal dichloroazomethine ylides to multiple carbon-carbon bonds

Doi:10.1007/s11178-005-0204-0
(2005)

Article Doi