Chemical Communications p. 9590 - 9593 (2017)
Update date:2022-08-11
Topics:
Ferreira, Renan B.
Figueroa, Jose M.
Fagnani, Danielle E.
Abboud, Khalil A.
Castellano, Ronald K.
Reported here is the first synthesis, X-ray crystal structure, and derivatization of benzotrifuran (BTFuran). Single crystal X-ray analysis of BTFuran shows a tight hexagonal packing stabilized by π-stacking interactions and C-H···O contacts. α-Lithiation of BTFuran enables the preparation of reactive intermediates suitable for cross-coupling reactions, allowing access to representative BTFuran-containing π-conjugated systems.
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