Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 199 - 206 (1989)
Update date:2022-08-23
Topics:
Hatano, Masaharu
Otsuka, Kiyoshi
Kinetic studies and isotopic exchange measurements (CH4-CD4 and 16O2-18O2) of the oxidative coupling of methane over stoichiometric LiNiO2 indicate a redox mechanism involving lattice oxygen atoms.The formation of C2 products is second-order in methane, both in the presence and absence of gaseous oxygen.Methane is dissociatively adsorbed on Ni3+-O2- sites, and the rate-determining step is the coupling of adsorbed CH3.Reduction of the catalyst by methane forms NiO, over which deep oxidation occurs.Adsorbed oxygen or gaseous oxygen is responsible for the deep oxidation.
View MoreQINGDAO NEW FLOURISH INTERNATIOANAL TRADE CO., LTD.
Contact:+86 532 80861829
Address:No. 1, Yinchuan East Road, 266061, Qingdao, China
Heliosense Biotechnologies, Inc.
website:https://www.heliosense.com/
Contact:+86-592-5667290
Address:Xiamen Torch Hi-tech Zone Venture Weiye Building S506
Chengdu ZY Biochemical Technology Co., LTD
Contact:0086-28-88680086
Address:170 Qingpu Road, Shouan Town, Pujiang County
Chengdu King-tiger Pharm-chem. Tech. Co., Ltd
Contact:028-85317716
Address:Tianfu Life Science Park, No. 88 South Keyuan Road, Gaoxin District, Chengdu City, Sichuan Province, PRC.
Hefei EnliPharma Tecnology Co.,Ltd
Contact:0086-551-66399836
Address:Qing Cheng ShuiXiang Building 805, Mengcheng North Road , ShuangFeng Economic Development Zone Anhui HeFei
Doi:10.1002/cctc.201901316
(2019)Doi:10.1016/j.tetlet.2006.03.038
(2006)Doi:10.1016/S0040-4020(01)00224-1
(2001)Doi:10.1021/ja00744a065
(1971)Doi:10.1021/jacs.9b00925
(2019)Doi:10.1080/00397910601038970
(2007)
