Activation of C-H Bonds in Saturated Hydrocarbons. H-D Exchange between Methane and Benzene catalysed by a Soluble Iridium Polyhydride System

DOI: 10.1039/c39860000801

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 801 - 802 (1986)

Update date:2022-08-16

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Authors:

Cameron, Charles J.

Felkin, Hugh

Fillebeen-Khan, Tauqir

Forrow, Nigel J.

Guittet, Eric

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Article abstract of DOI:10.1039/c39860000801

The soluble iridium pentahydride (i-Pr3P)2IrH5 (activated by t-Bu-CH=CH2) catalyses H-D exchange between C6D6 and CH4 under mild conditions.

Full text of DOI:10.1039/c39860000801

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