Journal of Chemical Physics p. 5184 - 5190 (1993)
Update date:2022-08-11
Topics:
Mason, Martin A.
Lehmann, Kevin K.
In the laser-induced fluorescence spectrum of HCP, a sharp decrease in fluorescence intensity was observed at 41 680 cm-1.This diminuation in emission intensity is due to a rotationally mediated coupling of the excited vibronic level with the dissociative continuum of the <*>X state; this has allowed us to place an upper limit on D0 for the ground electronic state.A lower limit for D0 can be placed at 41 650 cm-1 since strong emission was observed below this excitation energy.Using the assignments of Johns et al.
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