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ASSOCIATED CONTENT
Supporting Information.
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General experimental procedures; characterization de-
1
tails; and H, 13C and 19F NMR spectra of new com-
pounds (PDF)
X-ray crystallographic data (CIF)
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AUTHOR INFORMATION
Corresponding Author
*E-mail for S.C.: sbchang@kaist.ac.kr.
Notes
The authors declare no competing financial interest.
ACKNOWLEDGMENT
Andrade, M. M.; Teresa Barros, M. Chem.
−Eur. J. 2005, 11,
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Ley, L.; Hennrich, F.; Kappes, M.; Hirsch, A. J. Am. Chem. Soc. 2003,
125, 8566−8580. (e) Moon, S.; Kim, U. B.; Sung, D.; Kim, W. J. Org.
Chem. 2015, 80, 1856−1865. (f) Katsuki, T. Chem. Lett. 2005, 34,
1304−1309. (g) Bach, T.; Körber, C. Tetrahedron Lett. 1998, 39,
5015−5016. (h) Bach, T.; Körber, C. Eur. J. Org. Chem. 1999,
1033−1036. (i) Lu, H.; Subbarayan, V.; Tao, J.; Zhang, X. P. Organ-
ometallics 2010, 29, 389−393. (j) Uchida, T.; Katsuki, T. Chem. Rec.
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T.; Li, G.; Lu, H. J. Org. Chem. 2016, 81, 4898−4905.
(13) See the Supporting Information (SI) for detailed procedure on
the preparation of newly synthesized azidoformates. Explosion of
tert-butyl carbonazidate was reported to occur during its distillation:
Feyen, P. Angew. Chem., Int. Ed. Engl. 1977, 16, 115.
(14) (a) Kim, J. Y.; Park, S. H.; Ryu, J.; Cho, S. H.; Kim, S. H.;
Chang, S. J. Am. Chem. Soc. 2012, 134, 9110−9113. (b) Zhao, H.;
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7328−7333.
This article is dedicated to Professor Hiroaki Sasai on the occa-
sion of his 60th birthday. This research was supported by the Insti-
tute for Basic Science (IBS-R010-D1).
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