Journal of the American Chemical Society p. 8116 - 8121 (2020)
Update date:2022-08-11
Topics:
Liang, Xin-Ting
Chen, Jia-Hua
Yang, Zhen
An asymmetric total synthesis of (-)-spirochensilide A has been achieved for the first time. The synthesis features a semipinacol rearrangement reaction to stereoselectively construct the two-vicinal quaternary chiral centers at C8 and C10, a tungsten-med
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