CHANGES OF STEREOSELECTIVITY AND RATE IN DIELS-ALDER REACTIONS BY HYDROPHOBIC SOLVENT EFFECTS AND BY BOVINE SERUM ALBUMIN

DOI: 10.1016/0040-4039(88)85158-X

Source and publish data:

Tetrahedron Letters p. 3347 - 3350 (1988)

Update date:2022-08-10

Topics:

Authors:

Colonna, Stefano

Manfredi, Amedea

Annunziata, Rita

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Article abstract of DOI:10.1016/0040-4039(88)85158-X

The use of water instead of benzene as the solvent can strongly influence the stereoselectivity and the rate of Diels-Alder reactions of 1,4-naphthoquinone derivatives with different dienes.Enantiomeric exess (e.e.) up to 38percent is reached in the presence of a catalytic amount of bovine serum albumin.

Full text of DOI:10.1016/0040-4039(88)85158-X

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