
Tetrahedron p. 623 - 632 (1990)
Update date:2022-08-10
Topics:
Martins
Fourie
Venter
Wessels
The Clemmensen reduction of pentacyclo[6.4.0.02,7.03,11.0 6,10]= dodecane-9,12-dione unexpectedly led to the formation of pentacyclo[6.4.0. 02,6.05,9.04, 12]-2-dodecanol and pentacyclo[6.4.0.02,7.03,11.0 6,10]dode= cane-1,8-diol as main products. Tetracyclo[6.4.0.05,9.0412dodecane-2,7-dione and its corresponding hemiacetal were obtained as byproduc structures of the Clemmensen products were elucidated from an extensive 1H and 13C n.m.r. study.
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