A New Radical Based Synthesis of Lactams and Indolones from Dithiocarbonates (Xanthates).

DOI: 10.1016/0040-4039(94)88328-9

Source and publish data:

Tetrahedron Letters p. 1719 - 1722 (1994)

Update date:2022-08-11

Topics:

Authors:

Axon, Jonathan

Boiteau, Laurent

Boivin, Jean

Forbes, Judith E.

Zard, Samir Z.

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Article abstract of DOI:10.1016/0040-4039(94)88328-9

N,N-disubstituted α-(xanthyl)-acetamides with an olefin on one of the substituents undergo cyclisation to a lactam by a radical chain reaction involving transfer of the xanthate group; anilides lead to the corresponding indolones.

Full text of DOI:10.1016/0040-4039(94)88328-9

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