Stereocontrolled Total Synthesis of (+/-)-Isocomene and (+/-)-β-Isocomene via Ring Enlargement

DOI: 10.1039/c39850000898

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 898 - 899 (1985)

Update date:2022-08-11

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Authors:

Tobe, Yoshito

Yamashita, Toshiro

Kakiuchi, Kiyomi

Odaira, Yoshinobu

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Article abstract of DOI:10.1039/c39850000898

A total synthesis of (+/-)-isocomene (1) and (+/-)-β-isocomene (2) employing a chelation-controlled regioselective epoxide-carbonyl rearrangement as the key step has been realized.

Full text of DOI:10.1039/c39850000898

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