Radical cyclization of bromomethyldimethylsilyl propargyl ethers; A general method for the stereoselective synthesis of variously substituted trimethylenemethane (TMM) precursors

Article abstract of DOI:10.1080/00397919408011720

The radical cyclization of bromomethyldimethylsilyl propargyl ethers allows the regio- and stereoselective preparation of variously substituted 2- trimethylsilylmethyl-2-propen-1-ol derivatives in good yields. After acetylation of the alcohol function, th

Full text of DOI:10.1080/00397919408011720

This article was downloaded by: [University of Bristol]
On: 28 January 2015, At: 04:17
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number: 1072954
Registered office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH,
UK
Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
Publication details, including instructions for
authors and subscription information:
http://www.tandfonline.com/loi/lsyc20
Radical Cyclization of
Bromomethyldimethylsilyl
Propargyl Ethers; a
General Method for the
Stereoselective Synthesis
of Variously Substituted
Trimethylenemethane (TMM)
Precursors
Stéphane Bogen a , Michel Journet a & Max Malacria
a
a Université P. et M. Curie, Laboratoire de Chimie
Organique de Synthèse, Associé au CNRS , Tour
44-54, B. 229, 4 Place Jussieu, 75252, Paris, Cedex,
05, France
Published online: 23 Sep 2006.
To cite this article: Stéphane Bogen , Michel Journet & Max Malacria (1994) Radical
Cyclization of Bromomethyldimethylsilyl Propargyl Ethers; a General Method
for the Stereoselective Synthesis of Variously Substituted Trimethylenemethane
(TMM) Precursors, Synthetic Communications: An International Journal for
Rapid Communication of Synthetic Organic Chemistry, 24:9, 1215-1221, DOI:
10.1080/00397919408011720
To link to this article: http://dx.doi.org/10.1080/00397919408011720

PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of all the
information (the “Content”) contained in the publications on our platform.
However, Taylor & Francis, our agents, and our licensors make no
representations or warranties whatsoever as to the accuracy, completeness,
or suitability for any purpose of the Content. Any opinions and views
expressed in this publication are the opinions and views of the authors, and
are not the views of or endorsed by Taylor & Francis. The accuracy of the
Content should not be relied upon and should be independently verified with
primary sources of information. Taylor and Francis shall not be liable for any
losses, actions, claims, proceedings, demands, costs, expenses, damages,
and other liabilities whatsoever or howsoever caused arising directly or
indirectly in connection with, in relation to or arising out of the use of the
Content.
This article may be used for research, teaching, and private study purposes.
Any substantial or systematic reproduction, redistribution, reselling, loan,
sub-licensing, systematic supply, or distribution in any form to anyone is
expressly forbidden. Terms & Conditions of access and use can be found at
http://www.tandfonline.com/page/terms-and-conditions