Stereospecific Synthesis of α- and β-C-Aryl-Δ2-Glycopyranosides from p-tert-Butylphenyl α-O-Δ2-Glycopyranoside via Grignard Reagents

DOI: 10.1039/c39950001103

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1103 - 1104 (1995)

Update date:2022-08-17

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Authors:

Moineau, Christophe

Bolitt, Veronique

Sinou, Denis

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Article abstract of DOI:10.1039/c39950001103

Palladium-catalysed coupling of p-tert-butylphenyl α-O-Δ²-glycopyranoside with various substituted arylmagnesium bromides provides the corresponding C-α-aryl-Δ²-glycopyranosides, while nickel-mediated reaction allows the preparation of the C-β-aryl anomers.

Full text of DOI:10.1039/c39950001103

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