COORDINATION-SITE EXCHANGE REACTIONS OF SOME ACETYLACETONATO PALLADIUM(II) COMPLEXES: AUTOCATALYSIS AND SELF-CATALYSIS

DOI: 10.1246/cl.1981.769

Source and publish data:

Chemistry Letters p. 769 - 772 (1981)

Update date:2022-08-04

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Authors:

Tanaka, Hiroshi

Isobe, Kiyoshi

Kawaguchi, Shinichi

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Article abstract of DOI:10.1246/cl.1981.769

A novel type of palladium(II) complexes containing a chelated acetylacetonate anion, carbon-bonded pyridyl ligand, and triphenylphosphine were prepared.They umdergo the coordination-site exchange catalyzed by the phosphine freed from the reaction complex (autocatalysis) or the nitrogen end of the carbon-bonded pyridine in the reacting species (self-catalysis).

Full text of DOI:10.1246/cl.1981.769

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