REGIOSPECIFIC AND STEREOSELECTIVE CONVERSION OF RIBONUCLEOSIDES TO 3-DEOXYNUCLEOSIDES. A HIGH YIELD THREE-STAGE SYNTHESIS OF CORDYCEPIN FROM ADENOSINE.

DOI: 10.1016/S0040-4039(00)98716-1

Source and publish data:

Tetrahedron Letters p. 4295 - 4298 (1985)

Update date:2022-08-23

Topics:

Authors:

Hansske, Fritz

Robins, Morris J.

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Article abstract of DOI:10.1016/S0040-4039(00)98716-1

Treatment of 2',3'-anhydroadenosine (obtained in 92percent yield from adenosine) with lithium triethylborohydride (or deuteride) gave cordycepin (or its 3'(R)-deuterio derivative) in <*> 90percent overall yields with no 2'-deoxy isomer detected.

Full text of DOI:10.1016/S0040-4039(00)98716-1

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