Journal of the Chemical Society. Chemical communications p. 903 - 904 (1985)
Update date:2022-08-11
Topics:
Nishimura, Norio
Tanaka, Tohru
Sueishi, Yoshimi
The paretial molar volumes of trans-4-dimethylamino-4'-nitroazobenzene in solvents of different polarities are linearly related to the activation volumes in the same solvents for the thermal cis-trans isomerization of this species, which affords unequivocal evidence for an inversion transition state.
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