Evidence of an Inversion Mechanism for the Thermal cis-trans Isomerization of Push-Pull Azobenzenes. A Volumetric Study

DOI: 10.1039/c39850000903

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 903 - 904 (1985)

Update date:2022-08-11

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Authors:

Nishimura, Norio

Tanaka, Tohru

Sueishi, Yoshimi

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Article abstract of DOI:10.1039/c39850000903

The paretial molar volumes of trans-4-dimethylamino-4'-nitroazobenzene in solvents of different polarities are linearly related to the activation volumes in the same solvents for the thermal cis-trans isomerization of this species, which affords unequivocal evidence for an inversion transition state.

Full text of DOI:10.1039/c39850000903

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