Two-photon photodissociation of gaseous azulene at 325 nm

Article abstract of DOI:10.1063/1.463334

The two-photon photodissociation of gaseous azulene at 325 nm is reported.Acetylene is the major photodissociation product.The quantum yields for acetylene produced by irradiation of neat azulene at its normal vapor pressure and as a function of argon bath gas pressure are reported.The quantum yield of acetylene produced from irradiated azulene at its normal vapor pressure (ca. 10 m Torr) is ca. (5.85+/-1.46) * 10^-6.Using a mechanism by which internal conversion precedes the absorption of the second photon, the two-photon absorption cross section is calculated.

Full text of DOI:10.1063/1.463334

Twophoton photodissociation of gaseous azulene at 325 nm
S. Hassoon, D. L. Snavely, and I. Oref
Citation: The Journal of Chemical Physics 97, 9081 (1992); doi: 10.1063/1.463334
View online: http://dx.doi.org/10.1063/1.463334
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/97/12?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
130.88.53.18 On: Fri, 28 Nov 2014 07:55:25

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
130.88.53.18 On: Fri, 28 Nov 2014 07:55:25

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
130.88.53.18 On: Fri, 28 Nov 2014 07:55:25

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
130.88.53.18 On: Fri, 28 Nov 2014 07:55:25

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
130.88.53.18 On: Fri, 28 Nov 2014 07:55:25