Pure and Applied Chemistry p. 1189 - 1192 (1986)
Update date:2022-08-17
Topics:
Heller
Optically transparent films of metals are obtained if the particles constituting these are made much smaller than the wavelength of the transmitted light. Films consisting of 5 nm platinum particles, that are substantially transparent, have been prepared by photoelectrodeposition of platinum onto p-InP under mass transport limited conditions. The resulting hydrogen-evolving photocathodes convert sunlight to stored chemical energy at a 13% Gibbs free-energy efficiency. Photoelectrodeposition of similar platinum microcrystallites onto spinach chloroplast membranes, followed by transmission electron microscopy, opens the way to the mapping of photopotentials in these membranes.
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