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Dalton Transactions
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COMMUNICATION
Journal Name
results of CO2 adsorption indicate that not only the amount of
defects but also their charge-compensating groups within the
materials have a marked effect on the loading of guest
molecules. More importantly, the present work illustrates that
instead of exploring MOFs with new topologies and/or
functionalities, systematically tuning the defect concentration
and the compensating groups in frameworks is a powerful tool
to obtain novel materials for designed applications.
This research was supported by the Science and Industry
Endowment Fund (SIEF). The authors thank A/Profs. Chris
Sumby and Christian Doonan at the University of Adelaide, and
Prof. Cameron Kepert at the University of Sydney for
invaluable instrumental support. The authors also
acknowledge the facilities and the scientific and technical
assistance of the Australian Microscopy & Microanalysis
Research Facility at the Australian Centre for Microscopy &
Microanalysis at the University of Sydney. RB acknowledges
the computational facilities and services provided through the
CSIRO Advanced Scientific Computing, National Computing
Infrastructure (NCI) and Pawsey supercomputing facilities.
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