
Journal of the American Ceramic Society p. 135 - 139 (1985)
Update date:2022-08-16
Topics:
Osendi
Moya
Serna
Soria
The formation of metastable t-ZrO//2 by thermal treatment was studied in a systematic way on two different samples: a gel (G) and zirconyl acetate (A). The results show that initially nucleation of t-ZrO//2 is favored by creation of anionic vacancies with trapped electrons. At higher temperatures the electronic defects disappear, the crystallites grow, and the m-phase can nucleate.
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