EFFECT OF GUEST CATIONS ON THE PHOTO-SOLVOLYSIS OF 4'-(1-ACETOXY)ETHYLBENZO-15-CROWN-5

DOI: 10.1246/cl.1980.515

Source and publish data:

Chemistry Letters p. 515 - 516 (1980)

Update date:2022-08-16

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Authors:

Suzuki, Atsushi

Tada, Masaru

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Article abstract of DOI:10.1246/cl.1980.515

Photo-solvolysis of 4'-(1-acetoxy)ethylbenzo-15-crown-5 (1) in methanol is depressed by the complex formation of the crown ether moiety with alkali metal ions.This effect is accounted for by the destabilization of excited state of 1 and benzyl cation from 1.

Full text of DOI:10.1246/cl.1980.515

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