Zur Acetalbildung aus Alkoholen und Acetylen mit Platin- und Palladiumverbindungen als Katalysator

Article abstract of DOI:10.1016/0022-328X(91)86110-C

The platinum and palladium catalyzed addition of alcohols to acetylene to give acetals was investigated.The catalytic activity and productivity in dependence on the platinum compound and alcohol used, on the oxidation state of platinum and the cocatalytic effect of HCl are discussed.Systems of the type X2/HX (X = ClO4^-, BF4^-) are introduced as the first catalytically active palladium-containing systems.