Journal of the Chemical Society. Chemical communications p. 1008 - 1009 (1992)
Update date:2022-08-11
Topics:
Ishikawa, Masashi
Yamamoto, Kazuhiko
Fukuzumi, Shunichi
The formation of a transient radical ion pair has been detected directly in the reactions of 1,5-dihydroriboflavin-2',3',4',5'-tetraacetate (FIH2) with hydride acceptors (tetracyano-p-quinodimethane, tetracyanoethylene and p-benzoquinone derivatives) in deaerated acetonitrile, providing unequivocal evidence for an electron transfer pathway in the overall two-electron redox reactions of FIH2 with hydride acceptors.
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Doi:10.1021/ja003599b
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