Rotation mobility of the guest molecules and its reactivity in the thermal reaction in the solid matrix

Article abstract of DOI:10.1080/10587259408027169

Characteristic times of the thermal reaction and the molecular rotation for the guest molecules have been measured in polystyrene films. Rotation mobility of molecules was determined from the relaxation of the light induced optical anisotropy of the photoselected samples. Close agreement of the activation energies and characteristic times of thermal reaction and molecular rotation was observed. By the comparison of the induced optical anisotropy of the initial and photoconverted molecules the angles of the rotation of the molecular dipole transition moment in the instant of the elementary act of the photochemical conversion were determined.

Full text of DOI:10.1080/10587259408027169

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Molecular Crystals and Liquid Crystals
Science and Technology. Section A.
Molecular Crystals and Liquid Crystals
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The Rotation Mobility of the Guest
Molecules and its Reactivity in the
Thermal Reaction in the Solid Matrix
V. V. Minaylov a , A. Kh. Vorobiev a & V. S. Gurman a
a Moscow State University, Chemical Dept. , Moscow, Russia
Published online: 24 Sep 2006.
To cite this article: V. V. Minaylov , A. Kh. Vorobiev & V. S. Gurman (1994) The Rotation Mobility of
the Guest Molecules and its Reactivity in the Thermal Reaction in the Solid Matrix, Molecular Crystals
and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, 248:1,
97-101, DOI: 10.1080/10587259408027169
To link to this article: http://dx.doi.org/10.1080/10587259408027169
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