The kinetics of the reaction of OH with ClO

Article abstract of DOI:10.1063/1.444906

The rate constant for the reaction OH + radical-ClO -> Products (1) was measured in a discharge flow tube under pseudo-first order conditions in OH.OH was monitored via the resonance fluorescence detection scheme.The measurements were made at low pressures (ca. 1 Torr) and at temperatures between 248 and 335 K.The measured rate coefficients, corrected for the interference due to OH regeneration via the reaction Cl + HO2 -> OH + ClO, were found to be nearly temperature independent with a mean value of (1.17+/-0.33)x10^-11 cm³ molecule^-1 s^-1.

Full text of DOI:10.1063/1.444906

The kinetics of the reaction of OH with ClO
A. R. Ravishankara, F. L. Eisele, and P. H. Wine
Citation: J. Chem. Phys. 78, 1140 (1983); doi: 10.1063/1.444906
View online: http://dx.doi.org/10.1063/1.444906
View Table of Contents: http://jcp.aip.org/resource/1/JCPSA6/v78/i3
Published by the American Institute of Physics.
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Downloaded 13 Jun 2012 to 139.184.30.132. Redistribution subject to AIP license or copyright; see http://jcp.aip.org/about/rights_and_permissions

Downloaded 13 Jun 2012 to 139.184.30.132. Redistribution subject to AIP license or copyright; see http://jcp.aip.org/about/rights_and_permissions

Downloaded 13 Jun 2012 to 139.184.30.132. Redistribution subject to AIP license or copyright; see http://jcp.aip.org/about/rights_and_permissions