Journal of Physical Organic Chemistry p. 256 - 258 (1994)
Update date:2022-08-30
Topics:
Taskinen, Esko
Lindholm, Nina
The relative thermodynamic stabilities of 2-propenylbenzene (allylbenzene), and the E and Z forms of 1-propenylbenzene were determined over the temperature range 50-170 deg C by chemical equilibration in DMSO solution with t-BuOK as catalyst.The values of the thermodynamic parameters ΔG<*>, ΔH<*> and ΔS<*> at 298.15 K for each isomerization reaction between the title compounds were evaluated.
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