Synthesis of α-substituted α,β-unsaturated acylsilanes

DOI: 10.1016/S0040-4039(98)01219-2

Source and publish data:

Tetrahedron Letters p. 5937 - 5940 (1998)

Update date:2022-08-29

Topics:

Authors:

Tius, Marcus A.

Hu, Huaping

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Article abstract of DOI:10.1016/S0040-4039(98)01219-2

α-Deprotonation of tert-butyldimethylsilyloxy allene is followed by silyl migration from oxygen to carbon. The resulting C-nucleophile adds to aldehydes to generate α,β-unsaturated acylsilanes.

Full text of DOI:10.1016/S0040-4039(98)01219-2

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