Bulletin of the Chemical Society of Japan p. 2415 - 2419 (1983)
Update date:2022-08-12
Topics:
Sasamoto
Itoh
Sata
Activities and heats of mixing for the molten KCl-MnCl//2 system were determined mass-spectrometrically by the ion-current ratio method. Activities of components KCl and MnCl//2 show large negative deviations from Raoult's law, indicating a very strong interaction between KCl and MnCl//2. Entropies of mixing calculated from measured activities and heats of mixing have minimum values in the vicinity of 33% MnCl//2, and have been compared with those calculated on the basis of some molten structure models to infer possible chemical species in the molten salt.
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