Tetrahedron p. 3489 - 3494 (1980)
Update date:2022-08-16
Topics:
Burke, Basil A.
Chan, Wilfred R.
Honkan, Vidya A.
Blount, John F.
Manchand, Percy S.
A bicyclic diterpene cleomeolide (1), C20H30O3, has been isolated from Cleome viscosa L. (Capparaceae), and its stereostructure established by chemical, spectral and X-ray crystallographic means.Crystals of 1 belong to space group P21, with a=10.329(2)A, b=12.468(3)A, c=7.356(2)A, β=109.98 deg and Z=2.The structure was solved by a multiple solution procedure and refined by full matrix least-squares to give R=0.041 and wR=0.051.Oxidation of 1 gave the ketone 4, which on treatment with methanolic KOH led to a facile transannular reaction to give the lactone 6.
View Morewebsite:http://www.sigmaaldrich.com
Contact:800 558-9160
Address:Industriestrasse 25CH-9471 Buchs SGSwitzerland
Jingzhou TianHe Sci&Tech Chemical Co., Ltd.
Contact:86-716-8331612
Address:Jiangjin Road, #18, High-grade technology industries development district, Jingzhou city, Hubei province
Contact:+86-021-6989-5597
Address:No.80 Yichuan Rd., Putuo District,Shanghai,P.R.China
SuZhou Ascepion Pharmaceuticals, Inc.(expird)
Contact:0512-86881668
Address:Building C,68Xingqing Road,Suzhou,China.
Nanjing Capatue Chemical Co., Ltd
Contact:+86-25-86371192 +86-025-85720158
Address:No.20 Jiangjun Avenue, Jiangning Economic & Technical Development Zone
Doi:10.1021/ml900009d
(2010)Doi:10.1081/SCC-120005428
(2002)Doi:10.1016/S0040-4039(01)01572-6
(2001)Doi:10.1055/s-1993-25877
(1993)Doi:10.1021/ja00770a040
(1972)Doi:10.1016/S0040-4039(01)94152-8
(1972)